The calculated EFGs agree well with experimental PAC data, and indicate that shortly after the nuclear decay the structure relaxes from linear two-coordinate AgS 2 in the native protein, to a structure (or structures) where Cd( II) recruits additional ligands such as backbone carbonyl oxygens to achieve higher coordination number(s). Surprisingly, model systems truncated – as is often done – at the first C–C bond from the central Cd( II) are inadequate in size, and larger model systems must be employed to achieve reliable EFG calculations.
Note that 111Ag decays to 111Cd on which the PAC data are recorded. Next, this method was applied to model systems of the CueR protein, aiming to interpret 111Ag-PAC spectroscopic data. The results indicate that an error of up to around 10% on the calculated EFG may be expected using spin–orbit ZORA and the BHandHLYP functional with a locally dense basis set. Moreover, the available basis sets in ADF are tested in terms of basis set convergence, and the effect of including relativistic effects using the scalar relativistic and spin orbit ZORA Hamiltonians is explored. Urgent and vital, feeld composes a new and highly inventive lyrical narrative of what it means to live inside a marked body.With this work we first test various DFT functionals against CCSD(T) for calculation of EFGs at the position of Cd( II) in a very small model system, Cd(SCH 3) 2. Yet the knowledge, the explanation, never quite fits the sight. We know that the earth is turning away from it. "gendre is not the tran organe / gendre is yes a hemorage." "did u kno not a monthe goes bye / a tran i kno doesnt dye." The world of feeld is our own, but off-kilter, distinctly queer-making visible what was formerly and forcefully hidden: trauma, liberation, strength, and joy. Jos Charles’s ‘Feeld’ - The White Review REVIEW BY: July 2019 Jos Charles’s ‘Feeld’ In his book Ways of Seeing, John Berger wrote, ‘Each evening we see the sun set. FINALIST FOR THE PULITZER PRIZE FINALIST FOR THE LOS ANGELES TIMES BOOK PRIZE LONGLISTED FOR THE NATIONAL BOOK. In Charles's electrifying transliteration of English-Chaucerian in affect, but revolutionary in effect-what is old is made new again. Buy feeld by Jos Charles at Mighty Ape NZ. "i care so much abot the whord i cant reed." In feeld, Charles stakes her claim on the language available to speak about trans experience, reckoning with the narratives that have come before by reclaiming the language of the past.
Publisher Marketing: Selected by Fady Joudah as a winner of the 2017 National Poetry Series, Jos Charles's revolutionary second collection of poetry, feeld, is a lyrical unraveling of the circuitry of gender and speech, defiantly making space for bodies that have been historically denied their own vocabulary.
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